Hydrogen Sulfide and Maritime Safety
Recently, during a Port State Control inspection of an oil tanker, the personal gas safety meters of one member of the Coast Guard and one of the tanker crew went off when the crew member opened the valve to a pressurized tank holding Grade E Sour Crude. Sour crude oil contains a high amount of sulfur (over 0.5%), and some of this sulfur occurs as hydrogen sulfide (H2S) gas. Reported to have been standing no more than two feet downwind of the valve release, the Coast Guard member suffered severe H2S exposure symptoms over the next few days, resulting in renewed warnings by the Coast Guard on this serious danger.
You know that “rotten egg” hydrogen sulfide odor when you smell it at low levels, even below one part per million, but if you smell it in enough quantity, you probably won’t smell it for long. That’s because, at 100ppm or above, it quickly paralyzes the nerve centers inside your nose. If you don’t get away fast enough, other parts of your body become paralyzed, in the worst cases leading to unconsciousness, coma, and death. Even 10ppm may pose a health risk, and 50-100ppm is enough to overcome a person. At lower levels, H2S exposure symptoms include irritated eyes, nose, throat, and lungs. Higher levels of H2S include headache, dizziness, nausea, and vomiting. These symptoms may have a delayed onset of hours or days, as the unfortunate Coast Guard member mentioned above experienced.
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